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Biochars derived from various crop straws: characterization and Cd(II) removal potential.

Identifieur interne : 002351 ( Main/Exploration ); précédent : 002350; suivant : 002352

Biochars derived from various crop straws: characterization and Cd(II) removal potential.

Auteurs : Jingkuan Sun [République populaire de Chine] ; Fei Lian [République populaire de Chine] ; Zhongqi Liu [République populaire de Chine] ; Lingyan Zhu [République populaire de Chine] ; Zhengguo Song [République populaire de Chine]

Source :

RBID : pubmed:24859708

Descripteurs français

English descriptors

Abstract

Five types of biochars prepared from four crop straws and one wood shaving at 600 °C were characterized, and their sorption to Cd(II) were determined to investigate the differences in capacity to function as sorbents to heavy metals. Surface areas and pore volumes of the biochars were inversely correlated to the lignin content of raw biomass. The biochars derived from crop straws displayed more developed pore structure than wood char due to the higher lignin content of wood. Sorption capacity of the biochars to Cd(II) followed the order of corn straw>cotton straw>wheat straw>rice straw>poplar shaving, which was not strictly consistent with the surface area of the chars. The surface characteristics of chars before and after Cd(II) sorption were investigated with scanning electron microscopy equipped with an energy dispersive X-ray spectroscopy and Fourier transform infrared spectroscopy, which suggested that the higher sorption of Cd(II) on corn straw chars was mainly attributed to cation exchange, surface precipitation of carbonate, and surface complexation with oxygen-containing groups. This study indicated that crop straw biochars exhibit distinct sorption capacities to heavy metals due to various surface characteristics, and thus the sorption efficiency should be carefully evaluated specific to target contaminant.

DOI: 10.1016/j.ecoenv.2014.04.042
PubMed: 24859708


Affiliations:


Links toward previous steps (curation, corpus...)


Le document en format XML

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<term>Dépollution biologique de l'environnement (MeSH)</term>
<term>Lignine (analyse)</term>
<term>Microscopie électronique à balayage (MeSH)</term>
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<term>Oxydoréduction (MeSH)</term>
<term>Polluants du sol (métabolisme)</term>
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<div type="abstract" xml:lang="en">Five types of biochars prepared from four crop straws and one wood shaving at 600 °C were characterized, and their sorption to Cd(II) were determined to investigate the differences in capacity to function as sorbents to heavy metals. Surface areas and pore volumes of the biochars were inversely correlated to the lignin content of raw biomass. The biochars derived from crop straws displayed more developed pore structure than wood char due to the higher lignin content of wood. Sorption capacity of the biochars to Cd(II) followed the order of corn straw>cotton straw>wheat straw>rice straw>poplar shaving, which was not strictly consistent with the surface area of the chars. The surface characteristics of chars before and after Cd(II) sorption were investigated with scanning electron microscopy equipped with an energy dispersive X-ray spectroscopy and Fourier transform infrared spectroscopy, which suggested that the higher sorption of Cd(II) on corn straw chars was mainly attributed to cation exchange, surface precipitation of carbonate, and surface complexation with oxygen-containing groups. This study indicated that crop straw biochars exhibit distinct sorption capacities to heavy metals due to various surface characteristics, and thus the sorption efficiency should be carefully evaluated specific to target contaminant.</div>
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EXPLOR_STEP=$WICRI_ROOT/Bois/explor/PoplarV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 002351 | SxmlIndent | more

Ou

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 002351 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Bois
   |area=    PoplarV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     pubmed:24859708
   |texte=   Biochars derived from various crop straws: characterization and Cd(II) removal potential.
}}

Pour générer des pages wiki

HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i   -Sk "pubmed:24859708" \
       | HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd   \
       | NlmPubMed2Wicri -a PoplarV1 

Wicri

This area was generated with Dilib version V0.6.37.
Data generation: Wed Nov 18 12:07:19 2020. Site generation: Wed Nov 18 12:16:31 2020